 Solution

Forbidden emission lines arise from transitions strongly suppressed in the electric-dipole approximation, often between metastable levels. They can radiate in dilute gas because collisions are infrequent enough for a slow radiative decay to occur. In a two-level optically thin approximation, statistical equilibrium givesThe critical density of an atomic transition is $n_{\mathrm{crit}}=A_{ul}/q_{ul}$. At densities well below it, almost every collisional excitation radiates; above it, collisional de-excitation quenches the line relative to its low-density scaling. Collision coefficients and level populations determine the detailed multi-level diagnostic.

To measure temperature, compare lines of the same ion with significantly different upper-level excitation energies. The excitation coefficient contains a factor roughly $T^{-1/2}\exp [-\Delta E/(k_{B}T)]$ times a collision strength. The oxygen forbidden-line temperature diagnostic compares the relatively high-excitation $[\mathrm{O}\mathrm{III}]$ $4363$-angstrom line with the strong $4959$- and $5007$-angstrom lines. Their ratio is sensitive to electron temperature while canceling much of the common ionic abundance and emission measure.

To measure density, use upper levels with similar excitation energies but different radiative lifetimes and critical densities, as in $[\mathrm{S}\mathrm{II}]$ $6716/6731$. Their relative collisional quenching changes the ratio over an intermediate density range. At very low and very high densities the ratio approaches limiting values and loses sensitivity. A practical analysis fits density and temperature together, corrects wavelength-dependent extinction and calibration, checks blends and optical-depth assumptions, and uses reliable atomic transition and collision data. A single measured ratio generally constrains an emitting-gas model rather than proving every point of a nonuniform nebula has the same temperature.