 Solution

Use the course convention that a root system is finite and is a reduced root system satisfying the crystallographic root system condition. These hypotheses are essential for the angle restriction. For roots $r,s$, the two Cartan integerssatisfy $ab=4{\cos }^2\theta$. If $r,s$ are not parallel, the strict Cauchy-Schwarz inequality and integrality give $ab\in \{0,1,2,3\}$. These values give angles $\pi /2$, $\pi /3$ or $2\pi /3$, $\pi /4$ or $3\pi /4$, and $\pi /6$ or $5\pi /6$, respectively. If the roots are parallel, reducedness implies $s=\pm r$, giving $0$ or $\pi$. ThereforeHere are examples accounting for every angle. In the A1 root system, the pairs $(r,r)$ and $(r,-r)$ give $0,\pi$. Two roots from different summands of $A_1\oplus A_1$ give $\pi /2$. The six unit vectors at angles $k\pi /3$ form an A2 root system: taking one root at angle zero and another at $\pi /3$ or $2\pi /3$ gives those two angles. In the B2 root system $\{\pm e_1,\pm e_2,\pm e_1\pm e_2\}$, pair $e_1$ with $e_1+e_2$ or $-e_1+e_2$ to obtain $\pi /4,3\pi /4$. In a G2 root system, take short unit roots at angles $k\pi /3$ and long roots of length $\sqrt{3}$ at angles $\pi /6+k\pi /3$. A short root at zero paired with long roots at $\pi /6,5\pi /6$ gives the remaining angles.