 Solution

For $p+e\rightleftharpoons H+\gamma$, chemical equilibrium and the vanishing photon chemical potential imply ${\mu }_H={\mu }_p+{\mu }_e$. Taking the ratio of the three nonrelativistic Maxwell--Boltzmann number densities cancels these chemical potentials:The ground-state hydrogen atom has four combined electron and proton spin states if the small hyperfine splitting is ignored, whereas $g_p=g_e=2$. Hence $g_H/(g_p{g}_e)=1$. With Hydrogen binding energy $B=M_p+M_e-M_H$ and $M_H\simeq M_p$, the Saha ionization equation givesThe approximation in the prefactor neglects relative corrections of order $(M_e+B)/M_p$; the Hydrogen binding energy must be retained in the exponential.