 Solution

For a closed oriented $d$-dimensional manifold $M$ and a commutative coefficient ring $R$, Poincare duality says that cap product with the fundamental class is an isomorphismOver a field it equivalently gives a nondegenerate Poincare duality pairing $(a,b)\mapsto ⟨a⌣b,[M]⟩$ between complementary cohomological degrees.

For the six-manifold take rational coefficients and write $b_j={\dim }_{\mathbb{Q}}{H}^j(X;\mathbb{Q})$. Poincare duality gives $b_j=b_{6-j}$, so the Euler characteristic isThe middle-degree Poincare duality pairing on $H^3(X;\mathbb{Q})$ is skew-symmetric by graded commutativity of the cup product, since $(-1{)}^{3\cdot 3}=-1$. It is a nondegenerate alternating bilinear form, so its dimension $b_3$ is even. For example, a nonsingular skew-symmetric matrix of odd size would have $\det A=\det (-A)=-\det A$, impossible over $\mathbb{Q}$. Therefore $\boxed{\chi (X)\in 2\mathbb{Z}}$.

To realize every even integer, use $\chi (S^6)=2$, $\chi ({\mathbb{CP}}^3)=4$ and $\chi (S^3\times S^3)=0$. All three are closed connected orientable six-manifolds. For the connected sum of oriented manifolds, removing a ball from each summand and gluing their boundary spheres givesin dimension six: each removed open ball decreases the Euler characteristic by one, while the gluing sphere $S^5$ has Euler characteristic zero. If $k=2\ell$, putomitting zero copies. The Euler characteristic is $2+2r-2s=k$. This supplies a closed connected orientable example for every $k\in 2\mathbb{Z}$.

Without orientability, evenness need not hold. The Real projective space ${\mathbb{RP}}^6$ is a closed six-manifold with one cell in each dimension $0,\dots ,6$, soIt is nonorientable because the antipodal deck transformation on $S^6$ has degree $(-1{)}^7=-1$ and reverses orientation. Thus it gives the required counterexample.