Solution

ID: past-exam-of-the-mathematics-course-of-the-university-of-cambridge/2015/ii/paper-4/32c/iv/solution

The proposed Landau free energy has stationary equation . For its minimum is . For the minima are , while zero becomes a maximum; at the positive quartic term keeps the free energy bounded below. Thus the two symmetry-related states, continuous transition and square-root onset agree with the mean-field approximation.
More explicitly the mean-field entropy expansion gives at zero field. Near , replacing by in the quartic coefficient gives the positive constants and , and reproduces the preceding square-root amplitude. The polynomial is a local expansion near the transition, not a global expression at every temperature.

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