 Solution

Each bond of the classical Heisenberg antiferromagnet is minimized when its two spins are antiparallel. Since the periodic chain has an even number of sites, all bonds can be minimized simultaneously:The ground-state degeneracy is a continuous sphere of orientations $\hat{\mathbf{n}}\in S^2$. Choose the Néel state with even sites in $|S,S⟩$ and odd sites in $|S,-S⟩$.

This product state is not an energy eigenstate. The spin ladder operators inproduce states with both neighboring magnetic quantum numbers changed. On an up-down bond, $S_n^{-}{S}_{n+1}^{+}$ has a nonzero matrix element $2S$, hence coefficient $JS$ in the Hamiltonian. These orthogonal spin configurations show explicitly why the classical minimum is not an exact quantum eigenstate for $S>0$.