 Solution

Use the radial exponential $e^{-\alpha r}$ shown in the original PDF; the TeX's $e^{-\alpha x}$ is a transcription defect. Every orbital angular momentum operator annihilates a radial function, so it acts only on $P=x_1+x_2+2x_3$. The angular momentum of a radial function times a linear polynomial is determined by its degree-one angular factor: direct application of the rotation derivatives givesEquivalently its restriction to the sphere is a degree-one spherical harmonic. ThusFurthermore ${\hat{L}}_3\psi =-i\hslash K(x_1-x_2)e^{-\alpha r}$. Its expected value is proportional to the integral of $(x_1+x_2+2x_3)(x_1-x_2)e^{-2\alpha r}$. The cross terms are odd in a coordinate, and the integrals of $x_1^2$ and $x_2^2$ agree by rotational symmetry. HenceThe state need not be an eigenstate of ${\hat{L}}_3$. If normalization is desired, $\int P^2{e}^{-2\alpha r}{d}^{3}x=6\pi /{\alpha }^5$, so $K={\alpha }^{5/2}/\sqrt{6\pi }$; the zero expectation holds after normalization for any nonzero initial $K$.