 Solution

For $a>0$, the Brownian reflection principle gives, for $t>0$,where $\Phi$ is the standard normal distribution function. Hence $H_a<\infty$ almost surely; for $a=0$, $H_0=0$.

For $u\ge 0$, use the Exponential martingale for Brownian motion $Z_t=\exp (u{B}_t-u^{2}t/2)$. At $H_a\wedge t$, it is bounded by $e^{ua}$ because $B_s<a$ before the first hit and $B_{H_a}=a$ by continuity. The bounded optional stopping theorem gives $\mathbb{E}{Z}_{H_a\wedge t}=1$. Its limit is $e^{ua-u^2{H}_a/2}$, and the dominated convergence theorem yields $\mathbb{E}{e}^{ua-u^2{H}_a/2}=1$. Equivalently, the Brownian first-passage Laplace transform isTaking $\lambda =u^2/2$ proves the displayed exponential identity. The cases $u=0$ and $a=0$ are included. The restriction $u\ge 0$ is what gives the upper bound on the stopped exponential.