Solution

ID: past-exam-of-the-mathematics-course-of-the-university-of-cambridge/2018/ii/paper-2/36a/a/solution

In the canonical ensemble, a one-particle velocity state has kinetic energy and hence probability density proportional to , where . The three Cartesian Gaussian integrals normalize the density to the Maxwell-Boltzmann velocity distribution
Integrating over a spherical shell of radius and area gives the Maxwell speed distribution
Since
its unique positive maximum is the Most probable speed in the Maxwell distribution

New to topics? Read the docs here!