 Solution

Chemical equilibrium for $p+e^{-}\rightleftharpoons H+\gamma$ gives ${\mu }_p+{\mu }_e={\mu }_H$, because the photon chemical potential vanishes. Applying the nonrelativistic number-density formula to all three massive species and taking the ratio givesUse charge neutrality $n_p=n_e$, the Hydrogen binding energy $E_{\mathrm{bind}}=m_p{c}^2+m_e{c}^2-m_H{c}^2$, $m_H\simeq m_p$, and the ground-state statistical weights $g_H=g_p{g}_e$. ThenThe approximations are a dilute, nondegenerate ideal gas in thermal and chemical equilibrium, nonrelativistic electrons, protons and hydrogen, negligible excited hydrogen states, and negligible corrections from the proton-to-hydrogen mass ratio. This relation is the Saha ionization equation.