Solution

ID: past-exam-of-the-mathematics-course-of-the-university-of-cambridge/2021/ib/paper-1/14c/i/solution

For a normalized wavefunction obeying the infinite-wall Dirichlet boundary condition, integration by parts gives the energy expectation
Thus every energy eigenvalue is nonnegative.
For , the Time-independent Schrodinger equation and the wall conditions give
where and . Continuity of and at the finite potential step gives
Dividing and rearranging yields the bound-state quantization condition

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