Solution

ID: past-exam-of-the-mathematics-course-of-the-university-of-cambridge/2023/ii/paper-3/35a/b/iv/solution

For , the preceding density of states has
When , the Bose-Einstein distribution has the classical approximation
Each of the modes therefore contributes to the energy, so the Dulong-Petit law gives
When , the upper integration limit tends to infinity. The Bose integral
then yields
Hence the heat capacity at constant volume is
so . The high-temperature constant is the classical equipartition theorem result, while the low-temperature power law makes as required by the Third law of thermodynamics.

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