 Solution

Apply the product rule to the vector field $\Phi \nabla \Psi -\Psi \nabla \Phi$:The gradient cross terms cancel. Integrating and applying the divergence theorem with outward unit normal $\mathbf{n}$ proves Green's second identity:Choose the Dirichlet Green function $G_D(\mathbf{r},{\mathbf{r}}^{\prime })$ with ${\Delta }_{\mathbf{r}}{G}_D=\delta (\mathbf{r}-{\mathbf{r}}^{\prime })$ and $G_D=0$ on $S$. Taking $\Psi =G_D$ and using the Dirac delta distribution, the left side becomes $\Phi ({\mathbf{r}}^{\prime })$ while the second boundary term vanishes. HenceThe plus sign is tied to the convention $\Delta G_D=+\delta$, whose free-space fundamental solution is negative in three dimensions. The singularity may equivalently be handled by excising a small sphere about ${\mathbf{r}}^{\prime }$ before applying the smooth identity.