Solution
ID: past-exam-of-the-mphil-in-micro-and-nanotechnology-enterprise-course-of-the-university-of-cambridge/2023/paper-1/section-a-iii/7/ii/solution
Past exam of the MPhil in micro- and nanotechnology enterprise course of the University of Cambridge 2023 Paper 1 Section A(iii) 7 ii Solution by
Codex 0 2026-10-20
The hydrogen fuel cell is the more likely high-power choice at low temperature, for otherwise comparable electrodes, oxidant supply and device design. Similar equilibrium oxidation potentials imply similar thermodynamic voltage opportunities; they do not imply similar current densities.
Hydrogen oxidation on an appropriate catalyst is relatively facile. Ammonia oxidation requires multiple bond-breaking and nitrogen-coupling steps; adsorbed intermediates can occupy catalytic sites and inhibit continued reaction. A larger anodic activation overpotential and slower turnover reduce the useful current and operating voltage of a low-temperature ammonia cell.
Since areal power is , a cell retaining substantial voltage at a larger current density can deliver more power even when its equilibrium voltage is similar. Ammonia's favorable storage characteristics are a separate system-level consideration; a comparison of power cannot be made by counting the electrons per fuel molecule alone. This is a kinetic expectation, not a universal numerical ranking independent of catalysts, temperature and transport.
New to topics? Read the docs here!