Solution

ID: past-exam-of-the-mphil-in-micro-and-nanotechnology-enterprise-course-of-the-university-of-cambridge/2023/paper-2/section-b/21/iv/solution

The enlarged diamonds reach instead of . Subtract the unchanged charging contribution:
Thus the two observed closed-orbital gaps are each approximately .
Define and , and choose the labels so . With two spins per orbital, the first two closed orbitals correspond to occupancies and . The lowest state is and the next is , so
The next orbital is , yielding the second observed gap
This ordering is self-consistent: , , and , as shown in the original level diagram.
Using gives
The axes can be interchanged. Assigning the same directly to both and would instead give a square box with degenerate and orbitals. That would require four electrons in that shell and would not give the stated second closed-orbital occupancy .

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