The enlarged diamonds reach instead of . Subtract the unchanged charging contribution:Thus the two observed closed-orbital gaps are each approximately .
Define and , and choose the labels so . With two spins per orbital, the first two closed orbitals correspond to occupancies and . The lowest state is and the next is , soThe next orbital is , yielding the second observed gapThis ordering is self-consistent: , , and , as shown in the original level diagram.
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