Solution

ID: past-exam-of-the-physics-a-course-of-the-university-of-cambridge/2014/paper-1/section-a/1/solution

Write the one-electron Coulomb energies as , . The Pauli exclusion principle allows electrons in shell , including spin. The ground configuration therefore has two electrons in and seven in , giving . The least energy-increasing promotion is from to :
Rearranging the partly occupied degenerate shell does not produce a higher energy. Both total energies are negative, so this ratio is below one even though .

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