 Solution

Thermal bremsstrahlung is radiation from the acceleration of electrons in the Coulomb force of ions. At fixed temperature, the encounter rate per electron is proportional to ion number density $n_i$, and the number of radiating electrons per unit volume is $n_e$. Therefore $j_{\nu }\propto n_e{n}_i$ in a dilute, optically thin plasma. This is a binary-encounter rate, not a one-particle emission process.

For a fixed encounter geometry, the ionic electric field and hence the electron acceleration are proportional to ionic charge $Ze$. The Larmor formula is quadratic in acceleration, giving $j_{\nu }\propto Z^2$ at fixed species number densities. The dimensionless Gaunt factor $g(\nu ,T)$ corrects the simple classical result for the detailed quantum scattering and radiation calculation, after averaging over the thermal electron distribution. It depends on frequency and temperature and, in a more complete notation, ionic charge.