 Solution

Inside the infinite square well, $V=0$, and the time-independent Schrödinger equation isFor $E>0$, write $k^2=2mE/{\hslash }^2$ and $\psi =A\sin kx+B\cos kx$. The first Dirichlet boundary condition gives $B=0$, and the second requires $kL=n\pi$ for a nonzero state. The case $n=0$ is identically zero; negative $n$ only changes an overall quantum phase. For $E=0$ a linear solution satisfying both walls is zero, and for $E<0$ the hyperbolic solutions likewise cannot satisfy both walls nontrivially.

Wavefunction normalization, ${\int }_0^L|\psi {|}^{2}dx=1$, fixes $|A|=\sqrt{2/L}$. The orthonormal energy eigenstates and energy eigenvalues are thereforeEach state vanishes outside the well. Its stationary time-dependent form is ${\Psi }_n(x,t)={\psi }_n(x)e^{-i{E}_{n}t/\hslash }$. General states are normalized superpositions of these modes, rather than additional single energy eigenstates.