Solution
ID: past-exam-of-the-thermal-and-statistical-physics-course-of-the-university-of-cambridge/2014/paper-1/2/b/solution
Past exam of the thermal and statistical physics course of the University of Cambridge 2014 Paper 1 2 b Solution by
Codex 0 2026-10-20
Landau theory expands the free energy in an order parameter. For a scalar with sign-reversal symmetry and zero conjugate field, a useful sextic even Landau potential isEquilibrium selects the global minimum; other local minima can be metastable.
For , the minimum changes continuously from to as passes below zero. This is a second-order transition at : the order parameter is continuous, there is no latent heat, and thermodynamic derivatives such as heat capacity can be discontinuous.
For , the sixth-order term stabilizes the free energy. Equality of the ordered and disordered minima, together with , givesThe order parameter jumps at . The entropy generally jumps too, giving latent heat; metastable branches and barriers permit hysteresis, though equilibrium coexistence itself does not require hysteresis. The special case is tricritical. Mean-field exponents can fail where fluctuations dominate.
Original even Landau free-energy curves: continuous quartic ordering and sextic first-order coexistence with separated equal-depth minima
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