 Quasistatic spherical Stefan problem with capillarity

For a one-phase spherical Stefan problem with melting-temperature boundary value $T_s-\Gamma /a$ and supercooling $\Delta T=T_s-T_{\infty }>0$, use the latent-to-sensible heat ratio $S=\mathcal{L}/(c_p\Delta T)$. Large $S$ separates heat diffusion from slow interface motion. The exterior harmonic temperature is $T=T_{\infty }+(\Delta T-\Gamma /a)a/r$. The Stefan condition gives the displayed radius equation with $a_c=\Gamma /\Delta T$. This is the large inverse-Stefan number convention; the common sensible-to-latent Stefan number is $1/S$.