 Rational points need not generate the degree-zero Picard group

Let $C$ be the smooth projective model over ${\mathbb{F}}_2$ of $y^2+y=x^5+x+1$. Its only rational point is its unique point $p_{\infty }$ at infinity. At that point $x,y$ have pole orders two and five. The degree-two closed point $D$ defined by $y=0$, $x^2+x+1=0$ gives a nonzero class $[D-2p_{\infty }]$. Indeed a function with poles bounded by $2p_{\infty }$ has the form $a+bx$: in the affine coordinate ring every function is uniquely $A(x)+B(x)y$, and the two possible pole orders have opposite parity. No nonzero $a+bx$ vanishes at both roots of $x^2+x+1$. Thus the Abel map of a pointed smooth projective curve on rational points has trivial image here, but the degree-zero Picard group of a curve is nontrivial. Generation by point differences needs an algebraically closed field, or closed points with their residue degrees instead of just rational points.