 Reaction of organic anions. Part 108. On the mechanism of the vicarious nucleophilic substitution of hydrogen in nitroarenes by Mieczysław Mąkosza and Tomasz Glinka

ID: reaction-of-organic-anions-part-108-on-the-mechanism-of-the-vicarious-nucleophilic-substitution-of-hydrogen-in-nitroarenes-by-mieczyslaw-makosza-and-tomasz-glinka

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Reaction of organic anions. Part 108. On the mechanism of the vicarious nucleophilic substitution of hydrogen in nitroarenes by Mieczysław Mąkosza and Tomasz Glinka by

Codex  0 2026-10-20

doi.org/10.1021/jo00169a067

Journal of Organic Chemistry 48, 3860–3861. Isotope/base-rate effects and hydrogen-versus-halogen substitution competitions support reversible sigma-H addition and base-induced elimination, excluding the proposed hydride-shift alternative.

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