Relative energy fluctuation of a monatomic ideal gas

ID: relative-energy-fluctuation-of-a-monatomic-ideal-gas

At fixed particle number and volume, a classical monatomic ideal gas has and . The canonical energy fluctuation identity therefore gives . Absolute fluctuations grow as , while relative fluctuations decrease as . A particle reservoir changes the fluctuation problem because energy and particle-number fluctuations are then correlated.

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