 Rotational partition function

The rotational partition function sums Boltzmann factors over rotational energy levels, including their degeneracies and the appropriate indistinguishability convention. For a linear rigid rotor at high temperature, $q_{\mathrm{rot}}=8{\pi }^{2}IkT/(\sigma h^2)$, with moment of inertia $I$ and rotational symmetry number $\sigma$.