 Second-harmonic generation

Second-harmonic generation converts an incident optical frequency $\nu$ into $2\nu$ through a material's nonlinear response. In the photon description of an ideal lossless conversion, two input photons supply one output photon:Here $h$ is the Planck constant. The relation states conservation of energy; the material mediates the interaction. It does not say that each input photon independently splits its wavelength in half.

For vacuum wavelengths, ${\lambda }_{0,\omega }=c/\nu$ and ${\lambda }_{0,2\omega }=c/(2\nu )$, where $c$ is the speed of light. HenceThe second relation uses the refractive index for each propagating mode and frequency. Within a medium with optical dispersion, the wavelength need not halve. For an invented example, ${\lambda }_{0,\omega }=800\mathrm{nm}$, $n_{\omega }=1.5$, and $n_{2\omega }=1.6$ give $400\mathrm{nm}$ in vacuum, but in the material the two wavelengths are $533.33\mathrm{nm}$ and $250\mathrm{nm}$; their ratio is $0.46875$.