 Spin gap

A spin gap is a nonzero minimum energy required to reach a specified magnetic excitation above the ground state. One must specify which spin sector or measurement couples to that excitation; not every excitation gap is a spin gap.

Two antiferromagnetically coupled spin-$1/2$ particles illustrate it. For $H=J{\mathbf{S}}_1\cdot {\mathbf{S}}_2$ with dimensionless spin operators and $J>0$, the singlet has energy $-3J/4$ and the triplet has $J/4$, giving gap $J$. Thermal magnetic response is suppressed when $k_{B}T$ is well below that scale. Extended systems require their collective excitation spectrum rather than this isolated-pair argument alone.