Strong-bond limit of the alternating-spring chain
ID: strong-bond-limit-of-the-alternating-spring-chain
Take equal masses , atomic spacing , and alternating springs . The primitive unit cell contains a strong-bonded pair, so its length is and the Brillouin zone ends at . Expanding the exact alternating-spring chain dispersion relation givesThe low-frequency acoustic phonon branch moves almost rigid dimers of mass coupled by weak springs; its speed of sound tends to . The high-frequency optical phonon branch describes internal dimer stretch. At the zone edge the exact frequencies are and .
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