 Thermodynamic potential as a Lagrangian graph

For a smooth function $M(q)$, its differential defines a Lagrangian submanifold of the cotangent bundle: pullback of the canonical one-form on a cotangent bundle is $dM$, so pullback of the symplectic form $-d\theta$ is zero. The graph has half the ambient dimension. With $q=(S,V,N)$ and momentum coordinates $(T,-P,\mu )$, the first law of thermodynamics identifies the equilibrium graph with $dM$. This geometric statement does not require extensivity or thermodynamic stability.