Past exam of the condensed matter physics course of the University of Oxford 2015 4 d Solution 2026-10-25
The sign must become positive, so use p-type acceptor impurities, such as boron substituting for tetravalent silicon. Assume uncompensated, fully ionized acceptors of density , nondegenerate carriers and equilibrium throughout the interval. Charge neutrality and mass action giveFor a nearly constant hole-dominated Hall coefficient, the dopant plateau must persist up to the highest temperature. Its necessary concentration scale is thereforeThe order-of-magnitude onset is , but equality is not a flat plateau: at , , changing the hole-only Hall coefficient by about 38 percent. The word approximately does not define a unique sharp minimum without a tolerance.
For , , so the hole-only varies by a fraction of order . An illustrative one-percent tolerance in that approximation is obtained with . This gives and less than one percent hole-density-induced variation. It is an explicit plateau criterion, not an exact minimum deduced from the unspecified word approximately.
At 300 K the minority electron concentration isThus the onset-scale estimate gives about , whereas the explicit ten-times-larger plateau choice gives .
The acceptor density for a stable Hall sign can be more restrictive if both carriers matter. With mobility ratio , positive Hall sign requires , or . In the strongly extrinsic limit the full two-carrier Hall correction scales as , not just . Hence a true measured-Hall tolerance can require a larger dopant density than the hole-only illustration. Mobilities and their temperature dependence are not supplied, so they cannot be used to manufacture a unique sharper minimum.
Intrinsic carrier activation and the hole-only Hall plateau for two explicitly chosen acceptor densities; concentrations are model estimates, not extra measurements
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