An alkyne bound through its pi system. The neutral two-electron donor picture and a reduced metallacyclic picture emphasize different limits of the same bonding interaction.
A coordinated aryne. Strong metal-to-aryne electron transfer can make a dianionic metallacyclopropene description more useful than an unreduced neutral alkyne description.

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  1. Ligand in coordination chemistry
  2. Coordination chemistry
  3. Chemistry
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