Codex @codex  0

An interface between ordered domains related by a displacement that is a translation of the underlying disordered lattice but not of the ordered chemical structure. Slip by that displacement can leave an antiphase boundary behind a dislocation; a second appropriate displacement can restore the order.

The ordered $L{1}_2$ phase based on $\mathrm{N}{\mathrm{i}}_3\mathrm{Al}$ in many nickel-based superalloys. A matrix translation $a⟨110⟩/2$ disrupts its order and can create an antiphase boundary.

Resistance to dislocation motion caused by the energetic cost of disrupting chemical order, for example creating an antiphase boundary in a gamma prime phase precipitate.

The nickel-rich $\gamma$ matrix is a disordered substitutional solid solution on a face-centered cubic lattice. The ordered ${\gamma }^{\prime }$ phase has the L12 structure, approximately $\mathrm{N}{\mathrm{i}}_3\mathrm{Al}$: aluminium occupies cube corners and nickel occupies face centres. Its occupied-site geometry is often called ordered FCC, but its chemically labelled Bravais lattice is primitive cubic, with a four-atom basis. A face-centre translation exchanges chemical sublattices and is not a symmetry of the ordered crystal.

Each Al atom has twelve nearest-neighbour Ni atoms at Euclidean distance $a/\sqrt{2}$. Each Ni atom has twelve nearest neighbours too, but these are four Al and eight Ni. The chemical distinction matters for slip. In disordered $\gamma$, the shortest perfect Burgers vector isFor the ordered primitive cubic translation lattice, the shortest order-preserving perfect vector isThis does not imply that $⟨100⟩$ slip must dominate. A vector must lie in a favourable glide plane and have an accessible core structure and activation stress. Matrix dislocations commonly glide on $\{111\}⟨110⟩$ systems. A single $a⟨110⟩/2$ passage through ${\gamma }^{\prime }$ leaves an antiphase boundary; a second matching passage restores order, giving total vector $a⟨110⟩$. Such a superdislocation has a longer total vector than $a⟨100⟩$, yet its constituent dislocations can move on the favourable close-packed planes and interact with the matrix. Paired motion balances line and antiphase-boundary energies, so the shortest abstract lattice translation alone does not select the active slip system.^[ref]

At a common test temperature and otherwise comparable microstructure, chemical order generally raises the yield strength. An ordinary FCC dislocation displaced by $a⟨110⟩/2$ can interchange Au and Cu sublattices, creating an antiphase boundary behind it. This additional energy resists slip; paired dislocations can restore the order after the second member passes. The disordered phase does not pay the same ordering penalty. Comparing specimens actually tested at their different phase-stability temperatures also includes temperature-dependent mobility and recovery, so the ordering argument alone does not predict a unique measured strength ratio.

An order-preserving total dislocation in an ordered crystal, often dissociated into smaller dislocations separated by an antiphase boundary. Two matching $a⟨110⟩/2$ dislocations can restore order in the gamma prime phase.