Use calibrated multispectral imaging of reflected sunlight, with visible, near-infrared and short-wave-infrared bands. A satellite records radiance in several passbands for each ground pixel. Perform geometric registration and atmospheric correction to estimate spectral reflectance, then account for illumination differences on slopes and mask cloud, water and dense vegetation. A false-colour composite, diagnostic band ratios or a trained statistical classification can separate surface lithologies; field observations and representative spectra validate any mapped contact.
Different minerals have different absorption features: iron-bearing materials affect visible/near-infrared spectral reflectance, while hydroxyl-bearing clay minerals and carbonate-bearing rocks can differ in short-wave-infrared bands. Adjacent patches with reproducibly different spectra and coherent geological boundaries are candidates for lithological contacts. This is particularly useful in dry, exposed terrain. Vegetation, soil cover, similar rock compositions, weathering and topographic shadow can hide or mimic a contact; a colour boundary alone is insufficient.
Choose spatial resolution appreciably finer than the narrowest unit being mapped, with several pixels across that unit. Approximately – is suitable for regional contacts separated by hundreds of metres; metre-scale units require finer imagery or field work. Sentinel-2 provides – bands useful for this purpose, while the reflected-light multispectral bands of Landsat are typically . Broad multispectral passbands distinguish many rock assemblages but cannot resolve every narrow mineral absorption feature; hyperspectral imaging is preferable when those features are essential.
Many open-ocean chlorophyll retrieval algorithms infer chlorophyll a from the blue-to-green remote-sensing reflectance ratio. Increasing pigment generally depresses blue reflectance relative to green. In coastal waters, however, coloured dissolved organic matter and non-algal particles can independently absorb blue light, as in the sketches, and therefore mimic an increase in pigment. Their concentrations need not covary with phytoplankton biomass: river runoff and sediment resuspension can change them separately.
Moreover, the satellite measures emerging radiance, not absorption directly. Schematically,
where is the backscattering coefficient; this is an explanatory approximation, not a complete retrieval formula. Suspended particles change both absorption and backscattering, and different mixtures can produce similar band ratios. Shallow-bottom reflection, land-adjacency effects and more difficult atmospheric correction introduce further coastal errors. Consequently a simple blue/green ratio can overestimate chlorophyll a when excess CDOM removes blue light, although sediment scattering and other effects mean the bias is not universally positive. Multiband or hyperspectral methods that separately constrain pigment, dissolved absorption and particles, supported by local observations, are preferable in optically complex water.[ref]