Use calibrated multispectral imaging of reflected sunlight, with visible, near-infrared and short-wave-infrared bands. A satellite records radiance in several passbands for each ground pixel. Perform geometric registration and atmospheric correction to estimate spectral reflectance, then account for illumination differences on slopes and mask cloud, water and dense vegetation. A false-colour composite, diagnostic band ratios or a trained statistical classification can separate surface lithologies; field observations and representative spectra validate any mapped contact.
Different minerals have different absorption features: iron-bearing materials affect visible/near-infrared spectral reflectance, while hydroxyl-bearing clay minerals and carbonate-bearing rocks can differ in short-wave-infrared bands. Adjacent patches with reproducibly different spectra and coherent geological boundaries are candidates for lithological contacts. This is particularly useful in dry, exposed terrain. Vegetation, soil cover, similar rock compositions, weathering and topographic shadow can hide or mimic a contact; a colour boundary alone is insufficient.
Choose spatial resolution appreciably finer than the narrowest unit being mapped, with several pixels across that unit. Approximately – is suitable for regional contacts separated by hundreds of metres; metre-scale units require finer imagery or field work. Sentinel-2 provides – bands useful for this purpose, while the reflected-light multispectral bands of Landsat are typically . Broad multispectral passbands distinguish many rock assemblages but cannot resolve every narrow mineral absorption feature; hyperspectral imaging is preferable when those features are essential.

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