With length measured in units of , plot the real functionOnly the portions with can equal , so the strip between the horizontal lines and identifies allowed energy bands. The band edges of a repulsive delta-comb potential have the following approximate first intervals:Each interval corresponds to energy ; the intervening intervals are forbidden. The exact upper endpoints follow from . The lower endpoints solve inside . The divergence suggested by at the origin is removable, and , so there is no zero-energy state in the repulsive model.
Calculated delta-comb discriminant for barrier strength 10, with allowed bands marked by the strip between minus one and plus one
. Details. The periodic barriers produce separated energy bands and band gaps, unlike the continuous free-particle spectrum. A finite -atom loop has discrete states within these bands. Whether the material conducts still depends on band filling: one Electron per primitive cell half-fills a spin-degenerate band, while two Electrons per cell can fill the first band and place the Fermi energy in a gap. Band gaps alone do not establish that every filling is insulating. At high , the perturbing term becomes relatively small and the spectrum approaches free-electron behaviour in relative terms.
