Axial chirality 2026-10-14
An allene has a unit whose terminal substituents lie in perpendicular planes. In , with and , the two terminal pairs can define enantiomers without any tetrahedral carbon stereocenter. The groups need be different within each end pair, not all four mutually different. This is axial chirality.[ref]
Axial Chirality. Basic Terminology of Stereochemistry, entry Axial Chirality: nonplanar pairs about an axis, including allenes