Paul Ehrenfest Created 2026-10-31 Updated 2026-11-05
Paul Ehrenfest connected quantum expectation values with classical-looking equations of motion. For suitable quantum states evolving under the Hamiltonian , the Ehrenfest theorem gives and . Here is potential energy. The mean force need not equal the force evaluated at the mean position. If is a quadratic function, it does; for more general potential energy functions, a sufficiently narrow wave packet can justify an approximation. The theorem therefore states precisely which comparison between quantum mechanics and classical mechanics is exact and which step needs another assumption.[ref]
Figure 1.
Portrait of Paul Ehrenfest
. Historical photograph by an unknown photographer, held by the Noord-Hollands Archief. Listed as public domain by Wikimedia Commons. Source.