Past exam of the mathematics course of the University of Cambridge 2015 iii Paper 45 1 Solution Created 2026-10-03 Updated 2026-10-06
In Landau-Ginzburg theory, use the sextic even Landau potential with a fixed positive stabilising coefficient :Here is the scalar order parameter, its conjugate magnetic field, and an independent symmetry-preserving control, such as the single-ion coupling in the Blume–Capel model. Thus need not break , whereas does. The Blume–Capel mean-field tricritical parameters are one realization; generally, a tricritical point occurs whenTwo controls tune away the quadratic and quartic terms. For , crossing at gives a continuous phase transition; for , the quartic term instead favours a finite- minimum before the origin loses local stability. The sextic term bounds the free energy below. The tricritical point joins the continuous and discontinuous transition loci.
For the symmetric phase diagram, write . A nonzero stationary point obeys . Its free-energy density relative to the origin is . Equality of the two minimum values, together with stationarity, givesAt this phase coexistence point,so are genuinely degenerate global minima, not just stationary solutions. The spinodal points are for the disordered local minimum and for the appearance of the ordered minima. They are limits of metastability, distinct from the equilibrium first-order phase transition at .
Accordingly, the coefficient equations determining the physical temperature curves areThe simultaneous zeros of and determine and . For the alternative normalization , the same first-order condition is , with . These equations determine the curves implicitly; their slopes in actual coordinates depend on the material-specific coefficient functions.
In three controls , or locally equivalent coordinates, there are tricritical first-order wings. The plane contains a coexistence sheet of the two symmetry-related ordered phases. For it ends on the ordinary critical line ; for it reaches the three-phase line . Two further first-order surfaces extend from that line into and . Across a wing, two minima of the same sign but different magnitudes exchange global stability; the field favours that sign. Each wing ends on an ordinary critical edge where those minima and their intervening maximum merge. The three surfaces and their critical boundaries meet at the tricritical point.
The tricritical wing critical edges follow by imposing at :Here , confirming an ordinary quartic critical minimum locally. The field scale and the temperature-like displacement both vanish at the tricritical point. If are independent smooth local coordinates in , the following diagram has the same local topology as the physical three-dimensional phase diagram. Its surfaces use exact equal-minimum conditions, as described by tricritical wing coexistence factorization.
For the order-parameter critical exponent and critical-isotherm exponent at the tricritical point, set to leading order and take . For , the ordered saddle has , while at the equation of state is . Hence the tricritical mean-field critical exponents areThese are mean-field critical exponents. Below the tricritical upper critical dimension they need not be the interacting exponents, and at that dimension logarithmic corrections can accompany the powers. Along a generic path with the quartic term is subleading in the tricritical balance; a path keeping fixed instead approaches ordinary critical behaviour.
For the Blume–Capel model, take ferromagnetic , count each nearest-neighbour bond once and use hypercubic coordination . The nearest-neighbour direction sum in the printed Hamiltonian is understood implicitly. In a ferromagnetic mean-field approximation, write and replace the interaction by its self-consistent single-site field . The single-site partition function and variational free-energy density areThe first term prevents double counting the interaction energy. Differentiation gives the mean-field self-consistency equationSet and , the occupied-spin probability at . Expanding the single-site logarithm yieldsThe nontrivial simultaneous quadratic and quartic zeros require and , hence . At those values the sixth-order coefficient is , so the degeneracy is a stable tricritical point. The mean-field tricritical parameters areThis is a mean-field result, not a dimension-independent exact lattice transition temperature. The Boltzmann constant is kept explicit in this lattice calculation.
