Brillouin function 2026-10-25
The Brillouin function gives the normalized magnetization of independent angular-momentum- moments. It is odd, increasing, has slope at zero and tends to at large positive or negative argument. Explicitly,
It follows by differentiating the logarithm of , the one-ion partition function. Its limiting value gives magnetic saturation, and its initial slope gives the Curie law.
The terms in the Brillouin function cancel. Keeping the linear terms gives
Consequently,
Use the dimensionless SI magnetic susceptibility and , as in the source's molecular-field convention. The Curie law is
If susceptibility is instead defined as , its coefficient is and is dimensionful. The SI convention above makes the subsequent Curie–Weiss law and consistent.
The Brillouin function is odd, increases monotonically through zero, and approaches for . Its small- slope is . For , the magnetic ions overwhelmingly occupy the largest field-aligned moment projection, so the magnetization reaches magnetic saturation:
The sketch shows several values; all have the same limiting values, while their slopes differ.
For positive , a fluctuation of magnetization produces a Weiss molecular field in the same direction, reinforcing alignment. The mean-field self-consistency equation is
Linearizing in the paramagnetic phase gives
At zero applied field, the right-hand side's slope at is . Below this exceeds one, and the saturation of the Brillouin function allows stable nonzero solutions of opposite sign: spontaneous ferromagnetism. Above , only the zero-field solution remains stable. The stated linear susceptibility is the paramagnetic branch for ; it must not be continued as a negative susceptibility below the transition.