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False. Take $M={\mathbb{CP}}^2\#{\mathbb{CP}}^2$ and $N=S^2\times S^2$, with their standard product and connected-sum orientations. They are closed simply connected four-manifolds. For the connected sum, removing a four-ball leaves the fundamental group unchanged, and the Seifert-van Kampen theorem across the separating three-sphere preserves simple connectivity. The Mayer–Vietoris sequence computes integral cohomology $\mathbb{Z},{\mathbb{Z}}^2,\mathbb{Z}$ in degrees zero, two and four, and zero in other degrees. The Künneth theorem gives the same groups for $S^2\times S^2$. Thus their Betti numbers agree and all their integral cohomology is torsion-free.

Their cohomology rings nevertheless differ. In $M$, let $u,v$ come from the two projective summands and let $z$ generate degree four. The cohomology ring of the connected sum of two complex projective planes hasThese relations follow by using cycles in the separate summands and the degree-one pinch projections onto them. In $N$, the sphere-factor generators $x,y$ satisfyConsequently every degree-two class of $N$ has squarean even multiple of the top generator, whereas $u^2$ in $M$ is a primitive generator. An integral graded-ring isomorphism cannot change this property, since it sends a generator of $H^4$ to its positive or negative. A homotopy equivalence induces a graded-ring isomorphism, so none exists. Equivalently, their intersection forms are $\mathrm{diag}(1,1)$ and $\left(\begin{array}{cc}0& 1\\ 1& 0\end{array}\right)$, an odd form and an even form respectively.

Let $u_n$ be the rationalized universal class of degree $n$. The rational cohomology of an integral Eilenberg–MacLane space isHere $\Lambda$ is an exterior algebra. For $n=1$, $K(\mathbb{Z},1)\simeq S^1$. The standard path-loop spectral-sequence calculation supplies the induction: inthe total space is contractible and the fundamental fiber class transgresses to $u_n$. An odd exterior fiber generator gives an even polynomial base generator. An even polynomial fiber generator gives an odd exterior base generator; the differential on its $k$th power has coefficient $k$, which is invertible over $\mathbb{Q}$. The multiplicative spectral sequence then has no remaining positive-degree classes in the total space. This is the rational transgression calculation for Eilenberg–MacLane spaces; it includes the absence of additional base generators.

For $m=2n+1\ge 3$, choose $S^m\to K(\mathbb{Z},m)$ representing the integral fundamental class. The ring calculation shows that this map is a rational homology equivalence: both spaces have rational cohomology only in degrees zero and $m$. The rational Whitehead theorem for simply connected spaces identifies their rational homotopy groups. Since the target has only ${\pi }_m=\mathbb{Z}$, the rational homotopy groups of a sphere in odd dimension areFor $n=0$, this follows directly from ${\pi }_1(S^1)=\mathbb{Z}$ and the contractible universal cover of the circle, which makes every higher homotopy group zero.

Let $M={\mathbb{CP}}^2\#{\mathbb{CP}}^2$, with the standard complex orientations. It is simply connected by the Seifert-van Kampen theorem applied to the punctured summands. Classes $a,b\in H^2(M;\mathbb{Q})$ can be chosen from the two summands. Their cross product vanishes, while their squares equal the oriented top class:Thus the cohomology ring of the connected sum of two complex projective planes isThe two relations also kill all cubic monomials, so its dimensions are $1,2,1$ in degrees $0,2,4$ and zero otherwise.

We use the Sullivan minimal model dictionary: for a simply connected finite-type space, the dual of its degree-$i$ generator space is ${\pi }_i(M)\otimes \mathbb{Q}$. The following free graded-commutative differential algebra is the Sullivan model of the connected sum of two complex projective planes:It is minimal because all differentials of generators are decomposable.

To verify that no further generators are required, observe that $ab,a^2-b^2$ is a regular sequence in $\mathbb{Q}[a,b]$. The first polynomial is a nonzerodivisor. If $(a^2-b^2)h$ is divisible by $ab$, restricting to each coordinate axis forces $h$ to vanish on both axes, hence to be divisible by $ab$. The second polynomial is therefore a nonzerodivisor modulo the first. The Koszul complex of this regular sequence is exactly $\mathcal{M}$, so its cohomology is the quotient ring above, with no additional odd cohomology.

For completeness, choose rational polynomial forms representing $a,b$ on $M$. Their product and the difference of their squares are exact; choose degree-three primitives for them. Sending $r,s$ to those primitives defines a differential-algebra map from $\mathcal{M}$ to the rational polynomial forms on $M$. It induces the specified cohomology-ring isomorphism and hence is a quasi-isomorphism. This verifies the model directly, rather than assuming that a cohomology presentation alone automatically determines all rational homotopy.

The model has exactly two degree-two and two degree-three generators. Consequently the rational homotopy groups of the connected sum of two complex projective planes are