Series-termination quantization of the Coulomb radial equation Created 2026-09-24 Updated 2026-11-05
For an attractive Coulomb potential with , let be the relative-motion mass, using the reduced mass for a two-body system. A bound energy definesIn the orbital angular momentum sector , the Radial Schrodinger equation isExtract the regular origin power and decaying exponential by , with . Equating powers gives the recurrence relationThe regular confluent hypergeometric function otherwise contains an exponentially growing large-radius part. A physical bound state therefore requires termination: if has degree , then , soHere is the principal quantum number and counts positive radial nodes. For , the recurrence reduces to ; that denominator is an s-wave specialization, not the general angular-momentum recurrence. Regularity at the origin and normalizability at infinity are both essential boundary conditions.