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The equality $L\cap V_{\alpha }=L_{\alpha }$ can fail even at $\alpha =\omega +1$. Inside the constructible universe, $L_{\omega }=V_{\omega }$ is countable, so its definable power set $L_{\omega +1}$ is countable. The constructible power set of $\omega$ is uncountable there by the Cantor theorem. A real outside $L_{\omega +1}$ remains a constructible subset of $\omega$, hence belongs to $V_{\omega +1}$. The cardinal comparison must be made inside $L$, since its reals can be externally countable.

One can take $\boxed{\alpha =\omega +1}$. Finite induction gives $L_n=V_n$ for every finite $n$: every subset of a finite level is definable using its finitely many elements as parameters. Hence $L_{\omega }=V_{\omega }$, the set of hereditarily finite sets.

Now reason inside the constructible universe $L$, a model of ZFC. The set $L_{\omega }$ is countable there, and there are countably many first-order formulas and finite parameter tuples. Thus $L_{\omega +1}=\mathrm{Def}(L_{\omega })$ is countable in $L$. But the constructible power set ${\mathcal{P}}^L(\omega )$ is uncountable in $L$ by the Cantor theorem. ChooseThis $r$ is constructible and a subset of $\omega$, so $r\subseteq V_{\omega }$ and $r\in V_{\omega +1}$. ThereforeAll comparisons were made inside $L$; this avoids assuming that the constructible reals are uncountable in the ambient universe. The witness remains valid externally because the two structures use the same $r$, the same $V_{\omega }$, and the same constructible level. Thus constructible sets of low rank can appear at later stages.

The definable power set $\mathcal{D}(A)$ performs one definability step over the single structure $(A,\in )$, whereas the constructible power set ${\mathcal{P}}^L(A)$ contains subsets of $A$ created at arbitrarily late stages of the constructible hierarchy.

For the concrete case $A=\omega$, there are only countably many first-order formulas and finite tuples of natural-number parameters, so $\mathcal{D}(\omega )$ is a countable set. In contrast, the constructible universe satisfies ZFC, and Cantor theorem makes its full power set ${\mathcal{P}}^L(\omega )$ uncountable inside $L$. Consequentlyso the two notions do not agree in general.