Cup square after a diagonal sphere attachment ($u^2=-2v$)

For even $n\ge 2$, attach an $(n+1)$-cell to $S^n\times S^n$ along the diagonal. The cellular chain complex has boundary $(1,1)$ for the new cell. The degree-$n$ cohomology generator restricts to $a-b$, and the top generator restricts to $ab$. Naturality of the cup product therefore gives $u^2=-2v$, since $(a-b{)}^2=-2ab$. Thus the resulting cohomology ring is $\mathbb{Z}[u,v]/(u^2+2v,uv,v^2)$, with $|u|=n$ and $|v|=2n$. This distinguishes the attachment from a wedge of spheres, whose positive-degree products vanish.