The real scalar field has canonical momentum . Its Legendre transform gives
The first three terms constitute , the free massive Hamiltonian operator. The remaining term is . This sign is a consequence of having no time derivatives in the interaction: the canonical momentum is unchanged, while the interaction enters the Hamiltonian density with the opposite sign to the Lagrangian density.
In the interaction picture, operators evolve with and states evolve with constructed from the free interaction-picture field. Their evolution operator satisfies
Integrating once gives . Repeated substitution orders the integrations as . Replacing the ordered simplex by the full integration cube introduces and a time-ordered product, which proves the Dyson series
Taking the asymptotic limits with the usual adiabatic or regulated scattering prescription yields
The field in this expression is the free field evolving in the interaction picture, not an independently prescribed classical field. For quantum fields the expansion is a regulated perturbation series; the time-ordering symbol cannot be dropped because the operators at different times need not commute.
Use relativistically normalized two-particle states , with . The connected first-order scattering contribution is
Here the connected S-matrix uses a normalized vacuum and physical external one-particle states. At this order, normal ordering the vertex separates the four-external-leg contribution from vacuum and tadpole pieces; those disconnected or external-mass contributions are not the two-to-two scattering amplitude.
Two fields annihilate the incoming particles and two create the outgoing ones. There are choices of the annihilating fields, two assignments of the incoming momenta and two assignments of the outgoing momenta. Hence the total factor is , the external-leg factorial cancellation at a quartic scalar vertex. Each attachment contributes its plane-wave factor, so
The spacetime integral is the four-momentum conservation delta function, giving
In particular, the tree scattering amplitude is independent of angle.
For completeness, derive the relativistic two-body phase space in the centre-of-mass frame. Write , . The spatial delta function sets the two final momenta opposite, and the energy delta function is . Its radial Jacobian is . Thus
The invariant flux factor is for equal initial masses. Using , the labeled angular density is . The outgoing quanta belong to one real scalar field, so they are identical. A full-sphere integration counts each event twice and requires the identical final-state symmetry factor . Consequently
Equivalently one may integrate the labeled density over a hemisphere representing each event once. The final-state factor is separate from the vertex factorial: applying it at the vertex instead would give the wrong elastic scattering from a quartic scalar contact interaction cross-section.