Past exam of the chemistry A course of the University of Cambridge 2025 Paper 1 A4 d Solution 2026-10-20
The out-of-plane displacements in the wag transform as , hence as . A one-quantum combination of two distinct normal modes transforms as the product of their irreducible representations. The observed feature satisfiesA combination of the wag with an stretch has symmetry and can absorb through . In contrast, has no electric-dipole component in and is forbidden in the stated symmetry model. The missing feature near therefore identifies the stretch as .
The completed assignments areThe allowed combination obtains intensity through anharmonic/dipole-coupling terms; a purely separable harmonic model with a strictly linear dipole has no combination bands. The argument uses both the observed combination and the selection rule: absence of a feature by itself would not generally prove a forbidden symmetry.[ref]
Formaldehyde vibrational data in the NIST Chemistry WebBook. Gas-phase fundamentals: CH2 symmetric stretch 2783, antisymmetric stretch 2843, CO stretch 1746, wag 1167 cm−1, with the same symmetry convention