Fritz London 2026-10-20
Portrait of Fritz London
. GFHund, from the Friedrich Hund archive. CC BY 3.0. Source. London dispersion force 2026-10-20
Named after Fritz London, this is an attractive interaction between fluctuating electric dipoles of atoms or molecules, present even without a permanent dipole. At large separation compared with atomic size in the nonretarded regime, the dipole interaction scales as and its second-order ground-state energy correction is negative and scales as . Differentiating the energy gives an attractive force of magnitude . The short-distance overlap regime and the very-long-distance retarded regime require different descriptions.
