The addition energy has both charging and orbital terms,The larger diamonds indicate quantum dot shell closure after 2, 6 and 12 electrons. A two-dimensional isotropic harmonic oscillator confinement, , explains that sequence: shell has orbital states and capacity after spin degeneracy. The cumulative capacities are . Within a degenerate shell, the extra orbital term vanishes to this approximation; crossing a shell boundary costs an extra .
The gate capacitance lever arm is . Large and small gate widths differ by , so . Equivalently the tip energies differ by . Confinement anisotropy, exchange and disorder would split the ideal degeneracies; the diagram supports approximate shell symmetry rather than proving a perfectly parabolic potential.
Original spin-degenerate two-dimensional oscillator shell capacities and closed-shell electron counts
. Details. Assume the usual one-lead-biased measurement, with drain grounded and the gate referred to that ground; the printed map does not separately specify the wiring. This assumption is needed to assign individual source/drain capacitances. In this Coulomb diamond capacitance extraction, the smaller zero-bias gate intervals are 5 mV wide. In the constant interaction model with no orbital gap between those additions,An upper diamond tip lies at gate 123.75 mV between the zero-bias vertices 120 and 125 mV and at bias 2.50 mV. Its positive and negative edge slopes are therefore and . Reservoir alignment givesThe gate capacitance is not negligible in the second denominator. ConsequentlyThe consistency check is , matching the smaller tip's bias energy. The conventional electrostatic charging energy is 1.25 meV; it is half the charging energy contribution to the addition energy. A different applied-bias convention changes the slope formulas, so the convention must accompany the extraction.
