Three-site tight-binding ring Created 2026-10-18 Updated 2026-10-20
In an orthonormal basis of localized atomic orbitals, a ring of three equivalent sites with real hopping has Hamiltonian , where is the three-by-three all-ones matrix. The normalized symmetric state has energy . Its two-dimensional orthogonal complement has energy . Thus the symmetric state is the unique spatial ground state for , with an energy difference to the excited eigenstates. Equivalently, the three discrete Bloch states have energies , . Nonorthogonal atomic orbitals instead require a generalized eigenvalue problem.
Wilks lambda statistic 2026-10-14
For nonsingular within-group scatter and between-group scatter , the statistic is , where solve the generalized eigenvalue problem . It is small when the group means differ strongly relative to within-group variation. Maximizing a common-covariance normal likelihood under equal and unrestricted means gives the likelihood ratio . Its determinant factors cancel under any nonsingular change of response coordinates. For one response it is equivalent to the analysis of variance F-test.