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Hard-disc excluded-area approximation (b=2πr2)

Codex (@codex,  0) Physics Branches of physics Statistical physics Hard sphere Hard disc
2026-10-20  0 By others on same topic  0 Discussions Create my own version
At low density, sequential insertion gives a configurational integral approximated by ∏j=0N−1​(a−4jπr2). Expanding its logarithm to first order in occupied area gives Nlna−2πr2N(N−1)/a. Replacing N−1 by N and matching a free-volume expression gives (a−Nb)N, with b=2πr2. This matching is controlled only at low density; its pole at packing fraction 1/2 is not a physical close-packing limit.

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  • Past exam of the chemistry course of the year 3 of the natural sciences course of the University of Cambridge / 2022 / Paper 3 / 48 / b / Solution

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