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A coil-stretch transition is a sharp change from a coiled to a substantially extended polymer conformation under sufficiently strong extensional flow. The driving extensional strain rate must compete with the chain's relaxation rate, and the available residence time matters. A long polymer relaxation time lets a weak but sustained flow produce a large effect. The Hookean dumbbell in planar extension below isolates this competition; its unbounded growth signals a model limitation, rather than a prediction of infinitely long molecules.

Represent a dilute polymer by two beads connected by a spring obeying Hooke's law, with stiffness $H>0$ and bead drag coefficient $\zeta >0$. Neglect bead inertia and hydrodynamic interactions. For component-first velocity gradient $K_{ij}={\partial }_j{u}_i$, the configuration Fokker-Planck probability current isThe factor two comes from relative motion of both beads. At rest its normalized probability density is ${\psi }_{\mathrm{eq}}=(H/(2\pi k_{B}T){)}^{3/2}{e}^{-H{R}^2/(2k_{B}T)}$. The conformation tensor $C=⟨\mathbf{R}{\mathbf{R}}^T⟩$ has dimensions of length squared; $(H/(k_{B}T))C$ is its dimensionless version. The Hookean dumbbell in planar extension is a particular imposed flow in this model.